Metal Organic Frameworks of CPL-4 and CPL-5 Synthesis and Characterization under Magnetic Fields

Nasution, Hafni Indriati (2019) Metal Organic Frameworks of CPL-4 and CPL-5 Synthesis and Characterization under Magnetic Fields. Indonesian Journal of Chemical Science and Technology State University of Medan, 2 (1). pp. 61-65. ISSN 2622-4968

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CPL-4 and CPL-5 were synthesized with used 2,3 pyrazine dicarboxylic acid as main ligand , 4,4’-
azopyridine(Apy) as linker ligand for CPL-4 and 1,2-di-(4-pyridil)ethylene(Bpe) for CPL-5 in waterethanol(
1:1) and temperature 250C. Three methods used in various reaction time and dropping method to metal
ion with no stir treatment and also stirring or shaking treatment. CPL-4 have no magnetic field effect shows
same XRD pattern in all synthesis method. Otherwise, CPL-5 with used method#03 shows different XRD pattern
in 0T and 6T. By changing concentration of Cu2+ to 0.02 M, 6T crystal also shown different XRD pattern if
compared with 6T crystal with 2 hours to 1 hours reaction time. It indicate of changing reaction between Hpzdc
and Bpe with metal ion or reactivity both of ligand with metal ion induce different route under 6T. This process
may effect to new crystal structure during synthesis in 6T.

Item Type: Article
Keywords: main ligand; linker ligand; metal ion; magnetic fields
Subjects: H Social Sciences > HD Industries. Land use. Labor > HD9000 Special industries and trades > HD9506 Mineral industries. Metal trade
Q Science > QD Chemistry
Divisions: Fakultas Matematika dan Ilmu Pengetahuan Alam > Kimia
Depositing User: Mrs Elsya Fitri Utami
Date Deposited: 29 Feb 2020 02:43
Last Modified: 16 Mar 2020 07:13

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