Metal Organic Frameworks of CPL-4 and CPL-5 Synthesis and Characterization under Magnetic Fields

Nasution, Hafni Indriati (2019) Metal Organic Frameworks of CPL-4 and CPL-5 Synthesis and Characterization under Magnetic Fields. Indonesian Journal of Chemical Science and Technology State University of Medan, 2 (1). pp. 61-65. ISSN 2622-4968

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Official URL: https://jurnal.unimed.ac.id/2012/index.php/aromati...

Abstract

CPL-4 and CPL-5 were synthesized with used 2,3 pyrazine dicarboxylic acid as main ligand , 4,4’- azopyridine(Apy) as linker ligand for CPL-4 and 1,2-di-(4-pyridil)ethylene(Bpe) for CPL-5 in waterethanol( 1:1) and temperature 250C. Three methods used in various reaction time and dropping method to metal ion with no stir treatment and also stirring or shaking treatment. CPL-4 have no magnetic field effect shows same XRD pattern in all synthesis method. Otherwise, CPL-5 with used method#03 shows different XRD pattern in 0T and 6T. By changing concentration of Cu2+ to 0.02 M, 6T crystal also shown different XRD pattern if compared with 6T crystal with 2 hours to 1 hours reaction time. It indicate of changing reaction between Hpzdc and Bpe with metal ion or reactivity both of ligand with metal ion induce different route under 6T. This process may effect to new crystal structure during synthesis in 6T.

Item Type: Article
Contributors:
ContributionNameNIDN/NIDK
EditorHutabarat, Wesly195107201977101001
EditorDarmana, Ayi196608071990101001
Keywords: main ligand; linker ligand; metal ion; magnetic fields
Subjects: H Social Sciences > HD Industries. Land use. Labor > HD9000 Special industries and trades > HD9506 Mineral industries. Metal trade
Q Science > QD Chemistry
Divisions: Fakultas Matematika dan Ilmu Pengetahuan Alam > Kimia
Depositing User: Mrs Elsya Fitri Utami
Date Deposited: 29 Feb 2020 02:43
URI: http://digilib.unimed.ac.id/id/eprint/38525

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